Does your NAS have a case-sensitive file system on it? Most file systems are case-preserving but not case-sensitive. PM will have issues on case-sensitive file systems. But I would expect the same behavior for the Windows version which you state does work properly.
What would be an example of the file names for the image and the xmp file? Just write them down in your response, please.
Filenames are all in format: YYYY-MM-DD-XXXX.nef and YYYY-MM-DD-XXXX.xmp i.e. 2009-11-13-0001.nef and 2009-11-13-0001.xmp. As far as I checked, all filenames are in lower cases.
I'm not sure whether the NAS itself is case-senisitive, but under MacOS I cannot access files with wrong written cases, e.g. 2009-11-13-0001.xmp will work, 2009-11-13-0001.XMP doesn't work. Tested in the terminal.
What else is to say: the directories contain spaces in their names. In example for the structure is:
"/Volumes/archive/2009/2009-11-15 - 2. Worldcup 2009-2010/2009-11-15-0001.xmp". The NAS is mounted via AFP.
Lars