Hi Lars,
Thank you for the nice detective work in Lightroom's Export settings. I have also made some discoveries on why Photo Mechanic's metadata updates can cause the Synology Photos app not to display all of the image's metadata. If Photo Mechanic does not add any characters to the Exif Tag fields, Caption, Copyright and Photographer, then Synology Photos will not ignore all of the embedded metadata. Photo Mechanic can update any of the other fields without causing Synology Photos issues displaying the embedded metadata.
Best regards,
--Bob